Study on Arcing Phenomenon in Electroslag Remelting Process

11/09/2014 2:25pm

Автор: Shufeng Yang, Jing she Li, Wei Liu, Xiangzhou Gao, Gang Li,

Arcing often happens in the electroslag remelting(ESR) process and will lead arc point on the ingot surface which affect the quality seriously of ESR ingot. In this paper, the causes of arc point were analyzed for 200kg iron-chromium alloy ESR ingot and influence factors of causing arc point were studied by industrial experiment. The results show that the measures that control of low voltage and high current of the power system and using the Al 2O 3×24%+CaO×3%+CaF 2×70%+MgO×3% slag can prevent the generation of arc spot for the for 200kg iron-chromium alloy ESR ingot effetely and to improve the stability of the smelting process greatly.

Key Words: ESR, Arc spot, Power system, Refining slag

Study on Arcing Phenomenon in Electroslag Remelting Process

Shufeng Yang 1, Jing she Li 1, Wei Liu 1, Xiangzhou Gao, Gang Li 1,2

1School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing

2 Beijing Shougang GITANE, Beijing.

Introduction

 

The process, that the power pole was melted by the high temperatures which generated from the slag resistance region by the large current through, is called ESR process [1]. The main loop of the smelting process is composed of the electrode, slag pool, metal bath, steel ingot, tank bottom and short net and transformers [2]. The main circuit current is not smooth when the process parameters are instability sometime, which leads to divert traffic between the ingot and mold. If the divert traffic is too high in one place, the slag jacket will rupture, and arc discharge is generated due to the conduction between the ingot and mold, resulting the holes formed in the ingot surface [3]. At present, there were few reports on arcing phenomena in remelting process. In this paper, effect of power systems, the composition of slag and thickness of the slag layer on arcing was studied in electroslag remelting process.

Industrial Experiments

The electrodes used in this experiment are cast from smelting furnace, the diameter is 140mm, and the capacity of electroslag remelting furnace is 200kg. The main parameters of electroslag process were shown as Table I.
The arc points appearing in smelting process are shown as Figure 1. As can be seen from Figure 1, the ESR ingot body is impacted to produce some small holes. It brought to the defects for surface quality and internal organization of the ESR ingot, and is not conducive to the subsequent forging rolling process.

Table 1 Parameters in ESR smelting process

 


Ingot shape/kg

Smelting time/min

Amount of slag/kg

Thickness of lower slag layer /mm

Upper slag layer thickness/mm

Slag composition

200

82

12

95

110

24%Al 2O 3+5%CaO +71%CaF 2

Electrode diameter/mm

Voltage/V

Electric current/A

Water Pressure/MPa

Slow cooling method

Inlet pipe size/mm

140

55

5500

4

Sand burial

60


The arc points in  the ingot surfac

Figure 1. The arc points in the ingot surface


The ingot is cut along the position where the arc point appeared, and the sectional is pickled corrosion. It can be seen from Figure 2, the arc point has a certain depth, and dendrites along the direction of the arc point become equiaxed and extend to the core part. It can be inferred, arc phenomenon is generated that current breakdown from the ingot external to the internal. Dendrites are re-melted and then solidified by discharge phenomenon of the department, after the formation of it, and then the equiaxed is formatted because of the smaller thermal field gradient surrounding. The grain is large and loose, and undermines the continuity of the columnar grain. The arcs point is deep, and affects the finished product rate.
The instability of the process parameters, the series of problems caused by such as current, the furnace mouth voltage electrode buried depth and the gradual increase thickness of the slag layer, are likely to lead to arcing[4].


The arc points in the sectional of ingots

Figure 2. The arc points in the sectional of ingots

Results and Discussion

 

 

3.1 Power System

The power parameters are explored by regulating the voltage and current in smelting process. Current is less stable in the process that the process current increased from 5000A to 5500A, when voltage to 50V. The current is stability in the range 5200A-5300A in the process, when voltage to 45V. Metal pool depth and the depth of electrode buried is ideal match. This is because that, when the voltage is too high, the electrode buried depth will be too shallow, electro-slag process will become unstable, electrode will float in the slag surface, current will fluctuate, and the slag surface temperature will be too high. This will result that, gas and inclusion in ingot increased, burning of alloying elements increases, especially easily oxidized elements. Simultaneously it result the surface of the ingot is in a poor shape. Therefore, the ideal process parameters are determined as follow: voltage 45V, current 5250A (± 50 A).

3.2 Slag Composition

In order to study the effect of slag on arc points in the smelting process, the changing of the ratio of slag system were tested. The experimental schemes of different slag are shown in Table 2.

Table 2 Experimental schemes of different slag

 

 

Al 2O 3/%

CaO/%

CaF 2/%

MgO/%

Scheme 1

24

5

71

 

Scheme 2

20

5

75

 

Scheme 3

15

3

82

 

Scheme 4

15

8

77

 

Scheme 5

24

5

69

2

Scheme 6

24

3

70

3

The trial involved four kinds of components and the effect of slag component on thermo-physical properties of system is shown in Table 3:

Table 3 Thermo-physical properties of different slag components

 


Slag Component

Melting point /℃

Impact on the viscosity

Impact on conductivity

CaF 2

1270-1350℃

Reduced Significantly

Improve

CaO

2580℃

Reduced

Reduced

Al 2O 3

2050℃

Improve

Reduced Significantly

MgO

2852℃

Improve

Reduced

It is concluded through different slag experiments: 1) the establishment of the remelting process stabilizes gradually, when Al2O3 is from 24% to 15%. However, it leads to lower melting temperature of the slag, due to reducing significantly of the resistivity of the slag. And then the heat of the slag is not enough, quality problems is prone to generated, and the point of the arc is generated most likely in the surface of the ingot. 2) When a certain amount of MgO is added, slag smelting stability has improved to some extent, plastic and peeling slag clothing has been some improvement. 3) Since MgO and CaO increases the viscosity of the slag, a certain amount of the CaO content should be reduced while the amount of MgO added, in order to ensure that the slag having a certain degree of mobility. 4) Slag system is relatively stable in the smelting process of Scheme 6, and the ingot surface quality is better.

3.3 Thickness of the slag layer

It has taper along the axial of 200kg ingot mold, the cavity cross-section changes in time, which lead to the change of slag pool depth in melting process. Catchy is 210 mm and bottom is 240 mm, resulting the depth of catchy slag pool is 30% more than the bottom. The refining effect is different due to changes in the upper and lower slag pool depth. The appropriate amount of slag should be selected, so as to ensure the gap of smelting environment is smaller before and after. It is 5% -10% of the consumption residue accounts of slag clothing in the ingot surface (The slag clothing thickness is calculated as 0.5mm-1mm). Variations thickness of the slag layer in bottom and top with the amount of slag is shown as Table IV.
When the amount of slag is 12kg and 16kg, current has some fluctuated in smelting, and it is large in smelting late. When the amount of slag is 10kg, current is very stable in pre-stage, and it has a certain degree of volatility in late stage. When the amount of slag is 8kg, current is stable in pre-stage and mid-stage, and it has a slightly fluctuations in the latter.

 

Table 4 thickness of slag layer changes with different amount of slag


Amount of slag

the slag layer thickness of bottom

the slag layer thickness of top

8kg  

60-65 mm

80mm

10kg 

75-80 mm

95mm

12kg  

90-95 mm

110mm

16kg  

120 mm

140mm

When the amount of slag is 12kg and 16kg, there is more arcs point in the ingot surface. It still has a small amount of arc spot when the amount is 10kg. There is no arc spot when the amount is 8kg, and its surface quality is better. As can be seen from the above phenomenon, the thickness of slag layer is thicker, the molten metal bath is shallower, and the depth of the electrode buried reduces passive, lead to instability of the electrical parameters, thereby affecting the quality of ingot smelting. The correctness and rationality of the simulation, that the slag pool depth on the current density and temperature field is verified directly from the relationship between the stability of the current and the amount of slag.
Sum up, it is can be guaranteed a good stability of the electrical parameters, and also having good slag jacket peel ability, uniformity thickness of slag coat and better surface quality of ingot, what the amount of slag is 8kg.

3.4 Optimization Process

Based on the above results, the optimization smelting has been carried out, which the voltage is adjusted to 45V, current is controlled for 5250A (± 50 A), and  8kg slag Al 2O 3 × 24% + CaO × 3% + CaF 22 × 70% + MgO × 3% is used in the smelting process .The structure and surface of ingot after optimization is shown in Figure 3.
The structure and surface of ingot

Figure 3. The structure and surface of ingot after optimization smelting

 

As can be seen from Figure 7, columnar crystals distribute evenly and consistency, the surface is dense and smooth, quality is good, and there is not arc point of the ingot, after the process is optimized. Therefore, the optimization process can effectively verify and solve the problem of the arc point in ingot surface.

Conclusions

  • The low voltage and high current of the power system is advantageous to the stability of electroslag remelting smelting process. The ideal parameters of power system are voltage 45V and current 5250A (± 50 A) for 200kg ingot.
  • Using Al 2O 3×24%+CaO×3%+CaF 2×70%+MgO×3% slag can improve the stability of the smelting process and the smelting effect greatly.
  • The deep slag pool is prone to make arc phenomenon and can thin slag avoid generating arc effectively.It is can be guaranteed a good stability of the electrical parameters and also having good slag jacket peel ability, uniformity thickness of slag coat and better surface quality of ingot, what the amount of slag is 8kg for the 200kg ESR.

 

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Grant No. 51304016 )

References

 

  • Fu Jie, Chen Enpu, Zhu Jue. The Arcing of Slag pool in ESR Process[J]. ACTA METALLURGICA, 1965, 5(8): 8-16.
  • Huang Yongjie, Zhang Xiang, Ma Shaoxuan. Reasons and Solutions of Electric Leakage during ESR Process [J].Heilongjiang Metallurgy, 2001, 11(2): 24-26.
  • Wu M, Ludwig A. A three-phase model for mixed columnar-equiaxed solidification[J]. Metallurgical and Materials Transactions A, 2006, 37(5): 1613-1631.
  • Ballantyne A S, Kennedy R J, Mitchell A. The influence of melting rate on structure in VAR and ESR ingots[C]//reference source: Proc. 5. sup. th International Conf. Voc. Met. & ESR. 1976: 181-183.
  • Ballantyne A S, Kennedy R J, Mitchell A. The influence of melting rate on structure in VAR and ESR ingots[C]// Kr ger J G, Pl ckinger E, Winkler O, et al. Proceedings of the 5th Inter. Conf. on Vacuum Metallurgy and Electroslag Remelting Processes. Munich, Germany: Leybold-Heraeus GmbH &Co., 1976:181-183.


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